| 01/10/2000 | Away | Vicente Engonga | Athletic Club | 37 | 0-0 → 0-1 | 0.30 | - | - | - |
| 15/10/2000 | Home | Albert Luque | Racing de Santander | 52 | 0-1 → 1-1 | 0.27 | - | - | - |
| 15/10/2000 | Home | Carlos Domínguez | Racing de Santander | 86 | 1-1 → 2-1 | 0.57 | - | - | - |
| 21/10/2000 | Away | Albert Luque | RC Deportivo de La Coruña | 85 | 1-0 → 1-1 | 0.32 | - | - | - |
| 28/10/2000 | Home | Samuel Eto'o | FC Barcelona | 10 | 0-0 → 1-0 | 0.26 | - | - | - |
| 28/10/2000 | Home | Ariel Ibagaza | FC Barcelona | 51 | 1-0 → 2-0 | 0.15 | - | - | - |
| 01/11/2000 | Away | Ariel Ibagaza | Real Madrid CF | 55 | 0-0 → 0-1 | 0.36 | - | - | - |
| 01/11/2000 | Away | Carlos Domínguez | Real Madrid CF | 89 | 0-1 → 0-2 | 0.04 | - | - | - |
| 05/11/2000 | Away | Miguel Ángel Nadal | Real Sociedad | 89 | 0-0 → 0-1 | 0.61 | - | - | - |
| 12/11/2000 | Home | Finidi George | CD Numancia | 38 | 0-0 → 1-0 | 0.29 | - | - | - |
| 12/11/2000 | Home | Albert Luque | CD Numancia | 44 | 1-0 → 2-0 | 0.16 | - | - | - |
| 25/11/2000 | Home | Marcos | Villarreal CF | 57 | 0-1 → 1-1 | 0.29 | - | - | - |
| 25/11/2000 | Home | Álvaro Novo | Villarreal CF | 64 | 1-1 → 2-1 | 0.39 | - | - | - |
| 03/12/2000 | Away | Albert Luque | Real Zaragoza | 48 | 1-0 → 1-1 | 0.26 | - | - | - |
| 10/12/2000 | Home | Miguel Ángel Nadal | CA Osasuna | 56 | 0-1 → 1-1 | 0.28 | - | - | - |
| 17/12/2000 | Away | Ariel Ibagaza | Celta de Vigo | 23 | 1-0 → 1-1 | 0.23 | - | - | - |
| 17/12/2000 | Away | Javier Olaizola | Celta de Vigo | 89 | 2-1 → 2-2 | 0.33 | - | - | - |
| 20/12/2000 | Home | Marcos | RCD Espanyol | 19 | 0-1 → 1-1 | 0.24 | - | - | - |
| 20/12/2000 | Home | Fernando Niño | RCD Espanyol | 57 | 1-2 → 2-2 | 0.29 | - | - | - |
| 20/12/2000 | Home | Samuel Eto'o | RCD Espanyol | 83 | 2-2 → 3-2 | 0.53 | - | - | - |
| 07/01/2001 | Away | Ariel Ibagaza | Rayo Vallecano | 4 | 0-0 → 0-1 | 0.25 | - | - | - |
| 07/01/2001 | Away | Samuel Eto'o | Rayo Vallecano | 62 | 2-1 → 2-2 | 0.29 | - | - | - |
| 14/01/2001 | Home | Marcos | Deportivo Alavés | 27 | 0-0 → 1-0 | 0.27 | - | - | - |
| 14/01/2001 | Home | Ariel Ibagaza | Deportivo Alavés | 68 | 1-1 → 2-1 | 0.41 | - | - | - |
| 14/01/2001 | Home | Ariel Ibagaza | Deportivo Alavés | 80 | 2-1 → 3-1 | 0.10 | - | - | - |
| 14/01/2001 | Home | Álvaro Novo | Deportivo Alavés | 82 | 3-1 → 4-1 | 0.01 | - | - | - |
| 21/01/2001 | Away | Samuel Eto'o | Real Oviedo | 17 | 0-0 → 0-1 | 0.25 | - | - | - |
| 04/02/2001 | Home | Samuel Eto'o | Valencia CF | 17 | 0-0 → 1-0 | 0.25 | - | - | - |
| 04/02/2001 | Home | Albert Luque | Valencia CF | 89 | 1-2 → 2-2 | 0.33 | - | - | - |
| 11/02/2001 | Away | Rafa (OG) | Málaga CF | 30 | 0-0 → 0-1 | 0.29 | - | - | - |
| 18/02/2001 | Home | Carlos Domínguez | Athletic Club | 31 | 0-0 → 1-0 | 0.30 | - | - | - |
| 25/02/2001 | Away | Marcos | Racing de Santander | 40 | 1-0 → 1-1 | 0.25 | - | - | - |
| 03/03/2001 | Home | Samuel Eto'o | RC Deportivo de La Coruña | 2 | 0-0 → 1-0 | 0.28 | - | - | - |
| 03/03/2001 | Home | Ariel Ibagaza | RC Deportivo de La Coruña | 62 | 1-0 → 2-0 | 0.16 | - | - | - |
| 11/03/2001 | Away | Rivaldo (OG) | FC Barcelona | 52 | 0-0 → 0-1 | 0.35 | - | - | - |
| 18/03/2001 | Home | Albert Luque | Real Madrid CF | 38 | 0-0 → 1-0 | 0.29 | - | - | - |
| 01/04/2001 | Home | Samuel Eto'o | Real Sociedad | 24 | 0-0 → 1-0 | 0.27 | - | - | - |
| 08/04/2001 | Away | Ariel Ibagaza | CD Numancia | 65 | 0-0 → 0-1 | 0.41 | - | - | - |
| 08/04/2001 | Away | Lluís Carreras | CD Numancia | 89 | 0-1 → 0-2 | 0.04 | - | - | - |
| 15/04/2001 | Home | Gustavo Siviero | UD Las Palmas | 35 | 0-0 → 1-0 | 0.30 | - | - | - |
| 15/04/2001 | Home | Carlos Domínguez | UD Las Palmas | 89 | 1-1 → 2-1 | 0.61 | - | - | - |
| 22/04/2001 | Away | Lluís Carreras | Villarreal CF | 52 | 2-0 → 2-1 | 0.13 | - | - | - |
| 22/04/2001 | Away | Dani Güiza | Villarreal CF | 72 | 2-1 → 2-2 | 0.30 | - | - | - |
| 29/04/2001 | Home | Albert Luque | Real Zaragoza | 7 | 0-0 → 1-0 | 0.25 | - | - | - |
| 29/04/2001 | Home | Albert Luque | Real Zaragoza | 39 | 1-0 → 2-0 | 0.17 | - | - | - |
| 13/05/2001 | Home | Finidi George | Celta de Vigo | 47 | 0-0 → 1-0 | 0.32 | - | - | - |
| 13/05/2001 | Home | Finidi George | Celta de Vigo | 89 | 1-0 → 2-0 | 0.04 | - | - | - |
| 20/05/2001 | Away | Albert Luque | RCD Espanyol | 18 | 0-0 → 0-1 | 0.26 | - | - | - |
| 27/05/2001 | Home | Samuel Eto'o | Rayo Vallecano | 1 | 0-0 → 1-0 | 0.28 | - | - | - |
| 27/05/2001 | Home | Finidi George | Rayo Vallecano | 34 | 1-0 → 2-0 | 0.18 | - | - | - |
| 27/05/2001 | Home | Samuel Eto'o | Rayo Vallecano | 37 | 2-0 → 3-0 | 0.06 | - | - | - |
| 27/05/2001 | Home | Albert Riera | Rayo Vallecano | 89 | 3-0 → 4-0 | 0.00 | - | - | - |
| 10/06/2001 | Away | Miguel Ángel Nadal | Deportivo Alavés | 5 | 1-0 → 1-1 | 0.44 | - | - | - |
| 10/06/2001 | Away | Finidi George | Deportivo Alavés | 47 | 1-1 → 1-2 | 0.32 | - | - | - |
| 10/06/2001 | Away | Leonardo Biagini | Deportivo Alavés | 72 | 2-2 → 2-3 | 0.44 | - | - | - |
| 10/06/2001 | Away | Samuel Eto'o | Deportivo Alavés | 82 | 2-3 → 2-4 | 0.09 | - | - | - |
| 17/06/2001 | Home | Vicente Engonga | Real Oviedo | 37 | 0-0 → 1-0 | 0.30 | - | - | - |
| 17/06/2001 | Home | Samuel Eto'o | Real Oviedo | 58 | 1-0 → 2-0 | 0.16 | - | - | - |
| 17/06/2001 | Home | Ariel Ibagaza | Real Oviedo | 63 | 2-1 → 3-1 | 0.15 | - | - | - |
| 17/06/2001 | Home | Álvaro Novo | Real Oviedo | 89 | 3-2 → 4-2 | 0.04 | - | - | - |