| 23/09/2000 | Home | Paulo Jamelli | Deportivo Alavés | 41 | 0-2 → 1-2 | 0.11 | - | - | - |
| 23/09/2000 | Home | Yordi | Deportivo Alavés | 57 | 1-2 → 2-2 | 0.29 | - | - | - |
| 01/10/2000 | Away | Pablo Díaz Stalla | Real Oviedo | 82 | 2-0 → 2-1 | 0.07 | - | - | - |
| 28/10/2000 | Home | Daniel Montenegro | Málaga CF | 58 | 0-1 → 1-1 | 0.28 | - | - | - |
| 01/11/2000 | Away | Paulo Jamelli | Athletic Club | 23 | 0-0 → 0-1 | 0.27 | - | - | - |
| 01/11/2000 | Away | Jesús María Lacruz (OG) | Athletic Club | 89 | 1-1 → 1-2 | 0.61 | - | - | - |
| 05/11/2000 | Home | Daniel Montenegro | Racing de Santander | 38 | 0-0 → 1-0 | 0.29 | - | - | - |
| 05/11/2000 | Home | Paulo Jamelli | Racing de Santander | 57 | 1-0 → 2-0 | 0.16 | - | - | - |
| 19/11/2000 | Home | Marco Lanna | FC Barcelona | 42 | 0-0 → 1-0 | 0.31 | - | - | - |
| 19/11/2000 | Home | Paulo Jamelli | FC Barcelona | 50 | 1-0 → 2-0 | 0.15 | - | - | - |
| 19/11/2000 | Home | José Ignacio | FC Barcelona | 57 | 2-0 → 3-0 | 0.04 | - | - | - |
| 03/12/2000 | Home | Paulo Jamelli | RCD Mallorca | 4 | 0-0 → 1-0 | 0.25 | - | - | - |
| 09/12/2000 | Away | Juanele | CD Numancia | 44 | 1-0 → 1-1 | 0.26 | - | - | - |
| 16/12/2000 | Home | José Ignacio | UD Las Palmas | 65 | 0-0 → 1-0 | 0.41 | - | - | - |
| 16/12/2000 | Home | Juan Esnáider | UD Las Palmas | 73 | 1-1 → 2-1 | 0.45 | - | - | - |
| 16/12/2000 | Home | Yordi | UD Las Palmas | 80 | 2-1 → 3-1 | 0.10 | - | - | - |
| 20/12/2000 | Away | José Ignacio | Villarreal CF | 87 | 1-0 → 1-1 | 0.33 | - | - | - |
| 07/01/2001 | Away | Roberto Acuña | Real Sociedad | 82 | 1-0 → 1-1 | 0.32 | - | - | - |
| 14/01/2001 | Home | César Jiménez | CA Osasuna | 8 | 0-0 → 1-0 | 0.26 | - | - | - |
| 14/01/2001 | Home | José Ignacio | CA Osasuna | 16 | 1-0 → 2-0 | 0.18 | - | - | - |
| 14/01/2001 | Home | Juanele | CA Osasuna | 24 | 2-0 → 3-0 | 0.06 | - | - | - |
| 14/01/2001 | Home | Juan Esnáider | CA Osasuna | 59 | 3-2 → 4-2 | 0.16 | - | - | - |
| 21/01/2001 | Away | Martín Vellisca | Celta de Vigo | 24 | 1-0 → 1-1 | 0.23 | - | - | - |
| 04/02/2001 | Home | Paulo Jamelli | Rayo Vallecano | 22 | 0-0 → 1-0 | 0.28 | - | - | - |
| 04/02/2001 | Home | Juan Esnáider | Rayo Vallecano | 32 | 1-0 → 2-0 | 0.17 | - | - | - |
| 04/02/2001 | Home | Juanele | Rayo Vallecano | 46 | 2-0 → 3-0 | 0.06 | - | - | - |
| 04/02/2001 | Home | Marco Lanna | Rayo Vallecano | 51 | 3-0 → 4-0 | 0.01 | - | - | - |
| 04/02/2001 | Home | Roberto Acuña | Rayo Vallecano | 65 | 4-1 → 5-1 | 0.00 | - | - | - |
| 04/02/2001 | Home | Xavier Aguado | Rayo Vallecano | 85 | 5-1 → 6-1 | 0.00 | - | - | - |
| 18/02/2001 | Home | José Ignacio | Real Oviedo | 6 | 0-0 → 1-0 | 0.25 | - | - | - |
| 18/02/2001 | Home | Juan Esnáider | Real Oviedo | 23 | 1-0 → 2-0 | 0.18 | - | - | - |
| 18/02/2001 | Home | Martín Vellisca | Real Oviedo | 38 | 2-1 → 3-1 | 0.18 | - | - | - |
| 18/02/2001 | Home | Juan Esnáider | Real Oviedo | 44 | 3-1 → 4-1 | 0.06 | - | - | - |
| 18/02/2001 | Home | Roberto Acuña | Real Oviedo | 61 | 4-1 → 5-1 | 0.01 | - | - | - |
| 03/03/2001 | Home | Juan Esnáider | Valencia CF | 5 | 0-0 → 1-0 | 0.26 | - | - | - |
| 18/03/2001 | Home | Paulo Jamelli | Athletic Club | 18 | 0-0 → 1-0 | 0.26 | - | - | - |
| 18/03/2001 | Home | Juan Esnáider | Athletic Club | 28 | 1-1 → 2-1 | 0.29 | - | - | - |
| 01/04/2001 | Away | Juan Esnáider | Racing de Santander | 34 | 1-0 → 1-1 | 0.27 | - | - | - |
| 08/04/2001 | Home | Paulo Jamelli | RC Deportivo de La Coruña | 41 | 0-0 → 1-0 | 0.32 | - | - | - |
| 08/04/2001 | Home | Juan Esnáider | RC Deportivo de La Coruña | 81 | 1-0 → 2-0 | 0.09 | - | - | - |
| 14/04/2001 | Away | Juan Esnáider | FC Barcelona | 8 | 0-0 → 0-1 | 0.26 | - | - | - |
| 14/04/2001 | Away | Paulo Jamelli | FC Barcelona | 44 | 0-1 → 0-2 | 0.16 | - | - | - |
| 14/04/2001 | Away | José Ignacio | FC Barcelona | 74 | 1-2 → 1-3 | 0.12 | - | - | - |
| 14/04/2001 | Away | Juan Esnáider | FC Barcelona | 79 | 2-3 → 2-4 | 0.10 | - | - | - |
| 22/04/2001 | Home | Juanele | Real Madrid CF | 26 | 0-1 → 1-1 | 0.23 | - | - | - |
| 22/04/2001 | Home | Paulo Jamelli | Real Madrid CF | 60 | 1-2 → 2-2 | 0.29 | - | - | - |
| 29/04/2001 | Away | Paulo Jamelli | RCD Mallorca | 89 | 2-0 → 2-1 | 0.03 | - | - | - |
| 06/05/2001 | Home | Yordi | CD Numancia | 10 | 0-0 → 1-0 | 0.26 | - | - | - |
| 06/05/2001 | Home | Yordi | CD Numancia | 24 | 1-0 → 2-0 | 0.18 | - | - | - |
| 06/05/2001 | Home | Xavier Aguado | CD Numancia | 50 | 2-0 → 3-0 | 0.05 | - | - | - |
| 13/05/2001 | Away | Paulo Jamelli | UD Las Palmas | 34 | 0-0 → 0-1 | 0.29 | - | - | - |
| 27/05/2001 | Home | Gary Sundgren | Real Sociedad | 23 | 0-0 → 1-0 | 0.27 | - | - | - |
| 17/06/2001 | Home | Paulo Jamelli | Celta de Vigo | 58 | 0-1 → 1-1 | 0.28 | - | - | - |