| 17/09/2000 | Away | Pablo Lago | Real Oviedo | 70 | 1-1 → 1-2 | 0.42 | - | - | - |
| 23/09/2000 | Home | Eloy Jiménez | Real Valladolid | 51 | 0-1 → 1-1 | 0.26 | - | - | - |
| 01/10/2000 | Away | Þórður Guðjónsson | Valencia CF | 81 | 4-0 → 4-1 | 0.00 | - | - | - |
| 14/10/2000 | Home | Souleymane Oularé | Málaga CF | 76 | 0-1 → 1-1 | 0.33 | - | - | - |
| 14/10/2000 | Home | Orlando Suárez | Málaga CF | 83 | 1-1 → 2-1 | 0.53 | - | - | - |
| 22/10/2000 | Away | Antonio Guayre | Athletic Club | 10 | 0-0 → 0-1 | 0.26 | - | - | - |
| 22/10/2000 | Away | Álvaro | Athletic Club | 58 | 0-1 → 0-2 | 0.16 | - | - | - |
| 22/10/2000 | Away | Josico | Athletic Club | 89 | 0-2 → 0-3 | 0.00 | - | - | - |
| 28/10/2000 | Home | José María Ceballos (OG) | Racing de Santander | 28 | 0-0 → 1-0 | 0.29 | - | - | - |
| 28/10/2000 | Home | Souleymane Oularé | Racing de Santander | 82 | 1-1 → 2-1 | 0.52 | - | - | - |
| 12/11/2000 | Away | Antonio Guayre | Real Madrid CF | 34 | 2-0 → 2-1 | 0.14 | - | - | - |
| 18/11/2000 | Home | Orlando Suárez | RCD Mallorca | 86 | 0-0 → 1-0 | 0.57 | - | - | - |
| 26/11/2000 | Away | Jorge Larena | CD Numancia | 47 | 0-0 → 0-1 | 0.32 | - | - | - |
| 03/12/2000 | Away | Antonio Guayre | Real Sociedad | 75 | 0-0 → 0-1 | 0.46 | - | - | - |
| 09/12/2000 | Home | Antonio Guayre | Villarreal CF | 58 | 0-3 → 1-3 | 0.03 | - | - | - |
| 16/12/2000 | Away | Tomás Olías | Real Zaragoza | 69 | 1-0 → 1-1 | 0.31 | - | - | - |
| 20/12/2000 | Home | Antonio Guayre | CA Osasuna | 23 | 0-0 → 1-0 | 0.27 | - | - | - |
| 20/12/2000 | Home | Pablo Lago | CA Osasuna | 82 | 1-1 → 2-1 | 0.52 | - | - | - |
| 20/12/2000 | Home | Paqui | CA Osasuna | 89 | 2-2 → 3-2 | 0.61 | - | - | - |
| 07/01/2001 | Away | Souleymane Oularé | Celta de Vigo | 12 | 0-0 → 0-1 | 0.26 | - | - | - |
| 14/01/2001 | Home | Eloy Jiménez | RCD Espanyol | 27 | 0-0 → 1-0 | 0.27 | - | - | - |
| 21/01/2001 | Away | Pablo Lago | Rayo Vallecano | 28 | 0-0 → 0-1 | 0.29 | - | - | - |
| 04/02/2001 | Home | Souleymane Oularé | Real Oviedo | 73 | 0-0 → 1-0 | 0.45 | - | - | - |
| 25/02/2001 | Away | Robert Jarni | Málaga CF | 15 | 0-0 → 0-1 | 0.24 | - | - | - |
| 11/03/2001 | Away | Álvaro | Racing de Santander | 89 | 2-0 → 2-1 | 0.03 | - | - | - |
| 17/03/2001 | Home | Josico | RC Deportivo de La Coruña | 4 | 0-0 → 1-0 | 0.25 | - | - | - |
| 17/03/2001 | Home | Álvaro | RC Deportivo de La Coruña | 46 | 1-0 → 2-0 | 0.16 | - | - | - |
| 01/04/2001 | Away | Antonio Guayre | FC Barcelona | 7 | 0-0 → 0-1 | 0.25 | - | - | - |
| 15/04/2001 | Away | Antonio Guayre | RCD Mallorca | 44 | 1-0 → 1-1 | 0.26 | - | - | - |
| 22/04/2001 | Home | Eloy Jiménez | CD Numancia | 58 | 0-1 → 1-1 | 0.28 | - | - | - |
| 29/04/2001 | Home | Álvaro | Real Sociedad | 40 | 0-0 → 1-0 | 0.31 | - | - | - |
| 29/04/2001 | Home | Mario Turdó | Real Sociedad | 81 | 1-1 → 2-1 | 0.50 | - | - | - |
| 06/05/2001 | Away | Gabriel Schürrer | Villarreal CF | 50 | 2-0 → 2-1 | 0.11 | - | - | - |
| 13/05/2001 | Home | Orlando Suárez | Real Zaragoza | 65 | 0-1 → 1-1 | 0.28 | - | - | - |
| 13/05/2001 | Home | Orlando Suárez | Real Zaragoza | 72 | 1-1 → 2-1 | 0.44 | - | - | - |
| 20/05/2001 | Away | Antonio Guayre | CA Osasuna | 15 | 1-0 → 1-1 | 0.21 | - | - | - |
| 20/05/2001 | Away | Nacho González | CA Osasuna | 52 | 1-1 → 1-2 | 0.35 | - | - | - |
| 20/05/2001 | Away | Nacho González | CA Osasuna | 80 | 3-2 → 3-3 | 0.34 | - | - | - |
| 10/06/2001 | Away | Gabriel Schürrer | RCD Espanyol | 29 | 1-0 → 1-1 | 0.24 | - | - | - |
| 10/06/2001 | Away | Orlando Suárez | RCD Espanyol | 85 | 3-1 → 3-2 | 0.05 | - | - | - |
| 16/06/2001 | Home | Orlando Suárez | Rayo Vallecano | 22 | 0-0 → 1-0 | 0.28 | - | - | - |